Abstract: Scarcity of water resources in arid and semi-arid regions is the main reason limiting the effect of local ecological restoration, and adsorptive airborne water extraction technology has shown great potential in solving the problem of water demand of plants in ecological restoration, but fewer studies have been conducted on the application of this technology in this field at present. Therefore, in this study, NIPAM and AM were co-polymerized to form a new composite gel and loaded with hygroscopic salts to test the effects of gel ratios on the water absorption and release properties, as well as the performance under different temperature, humidity and light conditions, and water production in the field. The results showed that the composite gel with NIPAM∶AM mass ratio of 1∶1.5 had the optimal balance between water adsorption and water release, and the dissolution rate reached 24.7 g/g while 75.3% of water release could be realized, which was 31.3% more than the water production of the PNIPAM gel. Under the condition of temperature 20 °C and relative humidity (RH) 50%, the composite gel loaded with hygroscopic salt CaCl₂∶LiCl molar ratio of 1∶7 has the highest hygroscopicity, which is 1.14 times of that of the loaded pure LiCl gel, and can be hygroscopic under the condition of 30%−100% RH. The above optimized composite hygroscopic gel was applied to the ecological restoration project of mines in arid-semi-arid areas, and the average daily water yield in summer was about 0.74 g/g, which could make up for the shortfall of the ecological water demand of plants based on Penman's formula when the dosage was in the range of 14.1～17.6 g, which verified the feasibility of the application.